Abstract: The chemical constituents of ethyl ester extracts and n-butanol extracts from Litsea pedunculata were studied,and ten compounds were isolated by silica column chromatography and recrystallization.The structures of these compounds were elucidated as actinodaphnine(1),cassythicine(2),litseglutine A(3),boldine(4),norboldine(5),juziphin(6),reticuline(7),(+)-8,8′-epiaristo-ligone(8),kaempferol(9) and 5α,8α-epidioxyergosta-6,22-dien-3β-ol(10) by physical and chemical evidences and spectral methods.All the compounds were isolated from this plant for the first time.