Abstract: A method was established by high-performance liquid chromatography (HPLC-FLD) for determination of catechol,resorcinol,hydroquinone,phenol,o-cresol and (p+m)-cresol in flavor.The samples were enriched by two aqueous phase extraction(TAPS) of ionic liquid and then detected by high-performance liquid chromatography-fluorescence detector (HPLC-FLD).The enrichment factor of the method up to 20 and the whole operation process less than 15 min.In the range of 0.02—20 ng/mL,there was a good correlation (R2≥0.999 6) between the peak area and concentration of catechol,resorcinol,hydroquinone,phenol,o-cresol and (p+m)-cresol.The detection limits of phenols were 0.06,5.2,1.2,5.3,0.03 ng/L and 0.04 ng/L respectively.The relative standard deviations(RSD) were 1.4%—4.6% and the recoveries were 85.1%—96.9％.Compared with the previous methods,this method has good reproducibility,precision and lower detection limit.