Abstract: A new Pd(Ⅱ) ion-imprinted polymer particles were synthesized by precipition polymerization using ANA as functional monomer.And an ion imprinted carbon paste electrode (IIP-CPE) for the determination of Pd(Ⅱ) was prepared using the Pd(Ⅱ) ion-imprinted polymer particles as recognition material.The properties of the obtained IIP-CPE were researched by the amperometry method in 0.2 mol/L HAc-NaAc buffer solution (pH 3.6).The IIP-CPE showed high stability,good reproducibility,easy to update and simple to operation.The linear range for the determination of Pd(Ⅱ) using the IIP-CPE as working electrode was obtained as 0.028—40.8 μmol/L,and the detection limit was detected to be 0.017 μmol/L.The IIP-CPE was applied to determine the concentration of Pd(Ⅱ) in two real samples with the result of recoveries ranging from 97.5% to 102.8% and RSD of less than 4.8%.