叶艳青, 罗利军, 吴娜, 念晓, 张代云. 傣药竹叶兰中金属元素的形态分析[J]. 云南大学学报(自然科学版), 2009, 31(2): 187-190, .
引用本文: 叶艳青, 罗利军, 吴娜, 念晓, 张代云. 傣药竹叶兰中金属元素的形态分析[J]. 云南大学学报(自然科学版), 2009, 31(2): 187-190, .
Speciation analysis of metal elements in Arundina graminifolia by flame atomic adsorption spectrometry[J]. Journal of Yunnan University: Natural Sciences Edition, 2009, 31(2): 187-190, .
Citation: Speciation analysis of metal elements in Arundina graminifolia by flame atomic adsorption spectrometry[J]. Journal of Yunnan University: Natural Sciences Edition, 2009, 31(2): 187-190, .

傣药竹叶兰中金属元素的形态分析

Speciation analysis of metal elements in Arundina graminifolia by flame atomic adsorption spectrometry

  • 摘要: 照传统煎煮法对中药竹叶兰中铜、锌、铁、镁、钙、铬、锰和镉8种金属元素进行提取,用微孔滤膜分离提取液中的溶态与悬浮态,利用大孔吸附树脂柱对可溶态中的有机态与无机态进行分离;采用火焰原子吸收光谱法对各种形态中的8种元素进行测定.结果显示,竹叶兰叶中8种元素的总提取率10.27%~58.01%,浸留比11.46%~138.6%,悬浮态颗粒吸附率0.25%~8.47%,可溶态中铁的有机态与无机态的比例为322.8%,锌、镉、锰、镁、钙、铬和铜的有机态与无机态的比率40.28%~121.2%.该法对各元素的加标回收率93.48%~116.3%;相对标准偏差1.21%~3.57%,测定结果的精密度和准确度令人满意.

     

    Abstract: The eight elements Cu,Zn,Fe,Mg,Ca,Cr,Mn and Cd,in Arundina graminifolia were extracted based on traditional analytical flowchart program and separated into water-soluble state and suspension state by micro porous filtering film.Water-soluble state was divided into organic state and inorganic state based on macro porous adsorption resin.The elements were detected by flame atomic adsorption spectrometry(FAAS).The results show extractive rates of the elements were in the range of 10.27%—58.01% and immerse-residue ratio in11.46%—138.6%.Adsorption ration of suspension state was in the range of 0.25%—8.47%.The ratio of organic state to inorganic state of Fe in water-soluble state was 322.8%and the ratio of Zn,Cd,Mn,Mg,Ca,Cr and Cu were in the range of 40.28%—121.2%.The recovery ratios by standard addition were in the range of 93.48%~116.3% and relative standard deviations(RSD) were in the range of 1.21%—3.57%.Precision and accuracy of determining results are satisfactory.

     

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