殷彩霞, 肖涵, 高竹林, 黄荣, 张甦, 刘复初. (+)-4S,6R-对-(艹孟)-1-烯-6,8-二醇的简便合成[J]. 云南大学学报(自然科学版), 2005, 27(5): 437-439,450.
引用本文: 殷彩霞, 肖涵, 高竹林, 黄荣, 张甦, 刘复初. (+)-4S,6R-对-(艹孟)-1-烯-6,8-二醇的简便合成[J]. 云南大学学报(自然科学版), 2005, 27(5): 437-439,450.
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YIN Cai-xia, XIAO Han, GAO Zhu-lin, HUANG Rong, ZHANG Su, LIU Fu-chu. A facile synthesis of(4S,6R)-p-menth-1-ene-6,8-diol[J]. Journal of Yunnan University: Natural Sciences Edition, 2005, 27(5): 437-439,450.
Citation: YIN Cai-xia, XIAO Han, GAO Zhu-lin, HUANG Rong, ZHANG Su, LIU Fu-chu. A facile synthesis of(4S,6R)-p-menth-1-ene-6,8-diol[J]. Journal of Yunnan University: Natural Sciences Edition, 2005, 27(5): 437-439,450.
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(+)-4S,6R-对-(艹孟)-1-烯-6,8-二醇的简便合成

A facile synthesis of(4S,6R)-p-menth-1-ene-6,8-diol

    摘要
  • 摘要: 以α-蒎烯为原料,脂环酸钴作为催化剂,通入氧气,控制反应温度在80~90℃的条件下,意外地得到无色针状结晶化合物(+)—4S,6R-对-(艹孟)-1-烯-6,8-二醇,反应产率为6.6%,ee值为98.9%.经旋光仪测定,其旋光方向为右旋,其结构分别由IR,1HNMR,1CNMR,13C-1H-HMQC-2DNMR及MS波谱图的验证.

     

    Abstract: (+)-4S,6R-p-menth-1-ene-6,8,-diol was synthesized fromα-pinene in 6.6% yield.The compound was produced by oxidation ofα-pinene catalysed by cobalt alicyclic acid under the con-dition of molecular oxygen.Amount of the catalyst,reaction temperature and oxygen flow was also presented.The structure of the compound was identified by analysis of spectral data of IR,MS,1HNMR,1CNMR and 13C-1H-HMQC-2DNMR.

     

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