以邻菲罗啉为辅助配体的一维Cu(Ⅱ)配合物结构及磁性表征

Synthesis and magnetic properties of one demensional Cu(Ⅱ) complexes with phenanthroline as auxiliary ligands

摘要: 采用水热法合成了以叠氮钠和邻菲罗啉为配体的一维链状Cu(Ⅱ) 配合物,并通过元素分析、红外光谱、X射线单晶衍射和变温磁化率等技术对配合物进行了表征.该配合物属于三斜晶系,P1空间群,a=1.036 4(2),b=1.199 3(2),c=1.548 1(3)nm,α =87.70(3)°,β =84.58(3)°,γ =79.38(3)°,Z =1,V=1.882 3(7)nm3,d =1.735 mg/m3,F(000) =900.对该配合物的磁学性质进行了讨论.

Abstract: A novel one-dimensional Cu (Ⅱ) complex has been synthesized with sodium azide and phenanthroline as ligands by hydrothermal method and characterized by IR spectroscopy,elemental analyses,X-ray crystallography and magnetic susceptibility in this paper.The single crystal of this complex belongs to the triclinic space group P1 with a=1.036 4(2) ,b=1.199 3(2),c=1.548 1(3)nm,α =87.70(3)°,β =84.58(3)°,γ =79.38(3)°,Z =1,V=1.882 3(7)nm3,d =1.735 mg/m3,F(000) =900.Magnetic properties of this complex has been discussed.