金属锂枝晶生长机制及抑制方法进展

Research progress of growth mechanism and suppression methods of metal lithium dendrites

  • 摘要: 锂金属是高能量密度锂电池的理想负极材料,然而,锂枝晶的生长严重阻碍了其实际应用. 文章介绍了锂枝晶的主要生长模型(固态电解质膜保护生长模型、电荷诱导生长模型、薄膜生长模型等)、影响因素(温度、电流密度、电极过电位、固态电解质膜、沉积基底等)和先进表征技术(原位表征),并综述了近年来抑制锂枝晶生长的方法及研究进展(稳定沉积主体及表面修饰、固体电解质膜改性、使用高盐浓度和纳米化电解液、固体电解质等),最后,对锂金属电池的应用进行了评价和展望.

     

    Abstract: Lithium metal is an ideal anode material for high-energy-density Li metal batteries. However, the growth of lithium dendrites severely hinder the practical applications of the high-energy-density lithium metal anodes. This review introduces the growth models (such as solid electrolyte membrane protection growth model, charge induced growth model, and the thin film growth model), the influence factors (including temperature, current density, electrode overpotential, solid-state electrolyte film, and deposited substrate), and the advanced characterization technique (in situ characterization) of lithium dendrites, and summarizes the recent research progress about the inhibition of lithium dendrite growth (including the modification of the deposited substrate and solid electrolyte membrane, the usage of nanostructured electrolyte and the solid electrolyte). Finally, we give the prospect of commercial applications about lithium metal batteries.

     

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