孙座锐, 吉正元, 韩新宇, 史建武, 张晶, 张朝能, 宁平. 玉溪市城区大气VOCs及其它污染物质量浓度时空特征分析[J]. 云南大学学报(自然科学版), 2018, 40(4): 705-715. doi: 10.7540/j.ynu.20170654
引用本文: 孙座锐, 吉正元, 韩新宇, 史建武, 张晶, 张朝能, 宁平. 玉溪市城区大气VOCs及其它污染物质量浓度时空特征分析[J]. 云南大学学报(自然科学版), 2018, 40(4): 705-715. doi: 10.7540/j.ynu.20170654
SUN Zuo-rui, JI Zheng-yuan, HAN Xin-yu, SHI Jian-wu, ZHANG Jing, ZHANG Chao-neng, NING Ping. Spatial and temporal characteristics of atmospheric VOCs and other pollutants concentrations in urban air of Yuxi City[J]. Journal of Yunnan University: Natural Sciences Edition, 2018, 40(4): 705-715. DOI: 10.7540/j.ynu.20170654
Citation: SUN Zuo-rui, JI Zheng-yuan, HAN Xin-yu, SHI Jian-wu, ZHANG Jing, ZHANG Chao-neng, NING Ping. Spatial and temporal characteristics of atmospheric VOCs and other pollutants concentrations in urban air of Yuxi City[J]. Journal of Yunnan University: Natural Sciences Edition, 2018, 40(4): 705-715. DOI: 10.7540/j.ynu.20170654

玉溪市城区大气VOCs及其它污染物质量浓度时空特征分析

Spatial and temporal characteristics of atmospheric VOCs and other pollutants concentrations in urban air of Yuxi City

  • 摘要: 2014年8月至2015年7月在云南典型高原城市玉溪市5个监测点利用苏玛罐采样法采集VOCs样品,基于GC-MS分析方法获取了VOCs总质量浓度,同时利用空气自动监测设备监测了5个点位的大气NO2、CO、SO2、O3(最大8h)、PM10和PM2.5质量浓度.基于这些监测数据分析了玉溪市城区各种大气污染物的质量浓度分布特征及可能的来源.结果表明:监测期间玉溪市城区环境空气中VOCs、SO2、NO2、O3、PM10和PM2.5的平均质量浓度分别为(19.02±18.31)、(20.11±25.53)、(16.08±11.21)、(34.54±32.79)、 (49.51±34.09) μg·m-3和(28.67±20.85)μg·m-3,CO质量浓度为(1.35±0.82)mg·m-3.从季节分布来看,各种污染物变化规律并不一致.VOCs质量浓度呈现秋、春高,冬、夏低的特点,O3质量浓度呈现夏季高的明显特征,SO2质量浓度呈现冬、秋高,春、夏低的特征,NO2、CO、PM10和PM2.5质量浓度则表现为冬、春高,夏、秋低的特点.从空间分布特征来看,玉溪市中心交通密集区监测点大气环境中VOCs、NO2、O3、PM2.5和CO质量浓度较其他监测点浓度较高,反映机动车尾气的显著贡献;而工业区监测点大气环境中SO2和PM10质量浓度较高,符合工业燃煤排放烟气显著影响的基本特征.另通过相关性分析和气团轨迹研究表明除了本地人为活动影响外,区域传输源对玉溪城区大气污染有重要影响.

     

    Abstract: VOCs samples have been collected from 5 monitoring sites in Yuxi City from August 2014 to July 2015,and total VOCs have been obtained based on GC-MS analysis.At the same time,the mass concentrations of NO2,CO,SO2,O3 (maximum 8 h),PM10 and PM2.5 have been monitored by air automatic monitoring equipment.Based on these monitoring data,the characteristics of concentration distribution and possible sources of air pollutants in Yuxi City have been discussed.The results show that the average concentrations of VOCs,SO2,NO2,O3,CO,PM10 and PM2.5 in Yuxi are(19.02±18.31),(20.11±25.53),(16.08±11.21),(34.54±32.79)μg·m-3,(1.35±0.82)mg·m-3,(49.51±34.09)μg·m-3 and (28.67±20.85)μg·m-3.From the seasonal distribution,variation of various pollutants is not consistent.The concentration of VOCs is high in autumn and spring,low in winter and summer.The concentration of O3 is the highest in summer.The concentration of SO2 is high in winter and autumn,low in spring and summer.The concentrations of NO2,CO,PM10 and PM2.5 are high in winter and spring,low in summer and autumn.The concentration of VOCs,NO2,O3,PM2.5 and CO nearby the central traffics are higher than that of the other monitoring points,which reflects the significant contribution of the vehicle exhaust.The concentration of SO2 and PM10 in the industrial area is higher,which is a basic characteristic of the industrial with coal-fired.In addition,correlation analysis and an air mass trajectory show that the air quality of Yuxi City will be affected by the regional transmission sources.

     

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