马丹丹, 张洪彬. 樟脑型β-二羰基化合物的合成[J]. 云南大学学报(自然科学版), 2003, 25(5): 446-448.
引用本文: 马丹丹, 张洪彬. 樟脑型β-二羰基化合物的合成[J]. 云南大学学报(自然科学版), 2003, 25(5): 446-448.
MA Dan-dan, ZHANG Hong-bin. Synthesis of β-diketone from D-(+)-camphor[J]. Journal of Yunnan University: Natural Sciences Edition, 2003, 25(5): 446-448.
Citation: MA Dan-dan, ZHANG Hong-bin. Synthesis of β-diketone from D-(+)-camphor[J]. Journal of Yunnan University: Natural Sciences Edition, 2003, 25(5): 446-448.

樟脑型β-二羰基化合物的合成

Synthesis of β-diketone from D-(+)-camphor

  • 摘要: 天然樟脑在-83℃条件下与苯甲醛的羟醛缩合产物经过Swern氧化得到手性β-二羰基化合物.

     

    Abstract: A chiral β-diketone compound was synthesized from D-(+)camphor through Aldol reaction followed by Swern oxidation.The target compound was obtained in good yield and was characterized by IR, 1HNMR,13CNMR and MS.

     

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